CORROSION INDEX :
Ryznar
Stability
Index (RSI)
The Ryznar stability index (RSI) attempts to correlate an
empirical database of scale thickness observed in municipal water
systems to the water chemistry. Like the Langelier Saturation Index
(LSI), the RSI has its basis in the concept of saturation level.
Ryznar attempted to quantify the relationship between calcium
carbonate saturation state and scale formation. The Ryznar index
takes the form:
RSI = 2 pHs pH
Where:
- pH is the measured water pH
- pHs is the pH at saturation in calcite or calcium
carbonate
So, it gives an indication of the aggressive or encrusting trend
(scale-forming) water. And also an indication about the scale and
corrosion potential of the water.
The empirical correlation of the Ryznar stability index can be
summarized as follows:
- RSI < 6,5 water tends to be scale forming (the scale
tendency increases as the index decreases)
- 6,5 < RSI < 7 water is considered to be approximately at
saturation equilibrium with calcium carbonate
- RSI > 8 water is under saturated and, therefore, would tend
to dissolve any existing solid CaCO3 (mild steel corrosion becomes
an increasing problem)
Attached table given by the author (in French):
---------------------
Perconnal indication for aggressive and corrosive tendency:
Ryznar
index
|
Indication
|
<= 6.5
|
No aggressive
trend
|
> 6.5 and <=
7.2
|
Slight
aggressive
|
> 7.2 and <=
7.8
|
Slight corrosion (strong with
T> 60 °C)
|
> 7.8 and <=
8.5
|
Corosion so
T>15°C
|
> 8.5
|
Strong
corrosion
|